Capture of Ni(II), Cu(I) and Z(II) by thiolate sulfurs of an N2S2Ni complex: a role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site |
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| Authors: | Golden Melissa L Rampersad Marilyn V Reibenspies Joseph H Darensbourg Marcetta Y |
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| Affiliation: | Texas A&M University, Department of Chemistry, College Station, Texas, USA. |
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| Abstract: | The metal binding affinity of an (N2S2)Ni bridging metallothiolate ligand (Zn2+ < Ni2+ < Cu+) gives precedent for the observed heterogeneity in ACS/CODH. |
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