Reaction of vanadocene and vanadocene dichloride with ortho-iodobenzoic acid |
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Authors: | A. S. Gordetsov S. V. Zimina V. F. Ur’yash E. M. Moseeva |
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Affiliation: | 1682. Nizhny Novgorod State Medical Academy, pl. Minina i Pozharskogo 10/1, Nizhny Novgorod, 603005, Russia
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Abstract: | At the interaction of bis (η5-cyclopentadienyl)vanadium with iodobenzoic acid or trimethylsilyl o-iodobenzoate in toluene depending on the ratio of the initial reagents bis(η5-cyclopentadienyl)vanadium(o-iodobenzoate) or η5-cyclopentadienylvanadium-bis-o-iodobenzoate were obtained in high yields. The latter was also formed in the reaction of bis(η5-cyclopentadiene)vanadium dihloride with trimethylsilyl o-iodobenzoate. |
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