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A 3D network of helicates fully assembled by pi-stacking interactions
Authors:Vázquez Miguel  Taglietti Angelo  Gatteschi Dante  Sorace Lorenzo  Sangregorio Claudio  González Ana M  Maneiro Marcelino  Pedrido Rosa M  Bermejo Manuel R
Affiliation:Laboratorio di Chimica Supramolecolare, Dipartimento di Chimica Generale, Università di Pavia, 27100 Pavia, Italy. miguel.vazquez@unipv.it
Abstract:The neutral dinuclear dihelicate [Cu2(L)2] x 2CH3CN (1) forms a unique 3D network in the solid state due to pi-stacking interactions, which are responsible for intermolecular antiferromagnetic coupling between Cu(II) ions.
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