A zeolite-enzyme combination for biphasic dynamic kinetic resolution of benzylic alcohols |
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Authors: | Wuyts Stijn De Temmerman Karolien De Vos Dirk Jacobs Pierre |
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Institution: | Centre for Surface Chemistry and Catalysis, KULeuven, Kasteelpark Arenberg 23, 3001 Leuven, Belgium. |
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Abstract: | Acid zeolites like H-Beta are efficient heterogeneous catalysts for racemization of benzylic alcohols in water; by combination of the racemization with an enzymatic kinetic resolution in a two-phase system, enantiomerically pure esters were obtained in high yield via a dynamic kinetic resolution. |
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