Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO) |
| |
| Authors: | Baleizão Carlos Gigante Bárbara Das Debasish Alvaro Mercedes Garcia Hermenegildo Corma Avelino |
| |
| Institution: | INETI-Departamento de Tecnologia das Industrias Químicas, Estrada do Pa?o do Lumiar, 22, 1649-038 Lisboa, Portugal. |
| |
| Abstract: | A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si-CH2 groups anchored on the framework; this solid induces 30% enantioselectivity in the cyanosilylation of benzaldehyde. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
