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A novel Zn(II) complex based on 1H-1,2,3-benzotriazol-1-ylacetic acid and 1H-1,2,3-benzotriazole ligands: Synthesis, crystal structure, and photoluminescent property
Authors:T Wu  Y Gong
Institution:19575. Department of Chemistry, College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400030, P.R. China
Abstract:A novel complex formulated as Zn(HBTA)2(L)2] · 2H2O (I), where HL = 1H-1,2,3-benzotriazol-l-ylacetic acid, HBTA = 1H-1,2,3-benzotriazole, has been synthesized and structurally characterized by single crystal X-ray diffraction. Complex I shows a mononuclear structure, which is assembled into 1D chain via intermolecular π…π interactions and N-H…O hydrogen bonds. Different chains are linked by C-H…O hydrogen bonds into 2D layer. The photoluminescence property of the complex has been investigated.
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