Macropolyhedral boron-containing cluster chemistry. Synchrotron X-ray structural analysis of [(PMe2Ph)2Pd2B16H20(PMe2Ph)2] and [(PMe2Ph)3Pt2B16H18(PMe2Ph)]: models of intermediates to more condensed metallaboranes from the [(PMe2Ph)2PtB8H12] thermolysis system |
| |
| Authors: | Londesborough Michael G S MacLean Elizabeth J Teat Simon J Thornton-Pett Mark Kennedy John D |
| |
| Institution: | School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK. |
| |
| Abstract: | Thermolyses of (PMe2Ph)2PdB8H12] and (PMe2Ph)2PtB8H12] respectively yield eighteen-vertex (PMe2Ph)2Pd2B16H20(PMe2Ph)2] and (PMe2Ph)3Pt2B16H18(PMe2Ph)], which exhibit structure models for probable successive precursive intermediates for the more condensed macropolyhedral metallaboranes (PMe2Ph)4Pt3B14H16], (PMe2Ph)2Pt2B12H16] and (PMe2Ph)2Pt2B16H15(C6H4Me)(PMe2Ph)] that have previously been reported as products from (PMe2Ph)2PdB8H12] thermolyses. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
