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Improved charge transport in dye-sensitized solar cells employing viscous non-volatile electrolytes
Authors:Soon Hyung Kang  Moon-Sung Kang  Sang-Hyun Choi  Jae-Yup Kim  Hyun-Sik Kim  Taeghwan Hyeon  Yung-Eun Sung  
Institution:aSchool of Chemical and Biological Engineering and Interdisciplinary Program in Nano Science and Technology, Seoul National University, Seoul 151-742, Republic of Korea;bSamsung Advanced Institute of Technology, Energy and Environmental Laboratory, Gyeonggi-Do 446-712, Republic of Korea
Abstract:Dye-sensitized solar cells (DSSCs) employing a viscous non-volatile electrolyte were prepared by utilizing anatase TiO2 nanorods (synthesized via oriented attachment) as a photoanode material. One promising way to enhance the photovoltaic performance of DSSCs employing viscous electrolytes is to increase ion conductivity by increasing the salt concentration. This is accompanied by an acceleration of the charge recombination reaction and the limiting of the overall conversion efficiency. The results showed that a TiO2 nanorod electrode enables more favorable electron transport than a conventional nanoparticle-based electrode due to the improved electron diffusion length and the large intrinsic surface area.
Keywords:TiO2 nanorod  Dye-sensitized solar cell  Non-volatile electrolyte  Ion conductivity  Electron diffusion length
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