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Synthesis and structures of complexes ofN-2-nitroxyethylpicolinamide and 2-(2-pyridyl)-2-oxazoline with PdCl2 |
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| Authors: | B S Fedorov N I Golovina V V Arakcheeva M A Fadeev G V Strukov V V Kedrov G V Shilov L O Atovmyan |
| Institution: | (1) Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation |
| Abstract: | The reaction ofN,N′-bis(2-nitroxyethyl)pyridine-2,6-dicarboxamide with PdCl2 afforded previously unknowncis-(N-2-nitroxyethylpicolinamide-N,N′)dichloropalladium(II) andcis-2-(2-pyridyl)-2-oxazoline-N,N′]dichloropalladium(II), which were isolated as a cocrystallizate of the molecular compounds. Its structure was established by X-ray diffraction analysis. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1604–1606, August, 1999. |
| Keywords: | N N′ -bis(2-nitroxyethyl)pyridine-2 6-dicarboxamide reaction with palladium(II) chloride cis-(N-2-nitroxyethylpicolinamide-N N′ )dichloropalladium(II) cis-[2-(2-pyridyl)-2-oxazoline-N N′ ]dichloropalladium(II) crystal structure X-ray diffraction analysis |
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