Solid-state reactions of organometallic aldehydes with optically active primary β-hydroxyamines |
| |
Authors: | N S Khruscheva N M Loim V I Sokolov |
| |
Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation |
| |
Abstract: | The solid-state reactions of crystalline ferrocenyl- and ruthenocenylaldehydes with optically active primary β-hydroxyamines
were studied at ∼20 °C. The yield of the products increases substantially in the presence of K2CO3. The tautomeric equilibrium between imines and diastereomeric oxazolidines with the predominant formation of one of them
is established in solutions of the products in CDCl3.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2240–2243, December, 1997. |
| |
Keywords: | aldehydes primary β -hydroxyamines solid-state interaction tautomeric equilibrium stereoselectivity |
本文献已被 SpringerLink 等数据库收录! |