Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism |
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| Authors: | Samec Joseph S M Ell Alida H Bäckvall Jan-E |
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| Affiliation: | Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden. jeb@organ.su.se. |
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| Abstract: | The negligible double kinetic deuterium isotope effect (k(HH)/k(DD)= 1.05) in the reaction where [2,3,4,5-Ph4(eta5-C4COH)Ru(CO)2H (2) transfers a hydride and a proton to N-phenyl-[1-(4-methoxyphenyl)ethylidene]amine (4) indicates that no bond to hydrogen is broken or formed in the rate-determining step. |
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