Ruthenium(II) complexes containing triphenylphosphine/triphenylarsine and bidentate Schiff bases derived from 2-hydroxy-1-naphthaldehyde and primary amines |
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| Authors: | Kugalur P Balasubramanian Vaiapuri Chinnusamy Ramasamy Karvembu Karuppannan Natarajan |
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| Institution: | (1) Department of Chemistry, Sri Ramakrishna Mission Vidyalaya College of Arts and Science, Coimbatore, 641 020, India;(2) Department of Chemistry, Bharathiar University, Coimbatore, 641 046, India |
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| Abstract: | The synthesis and characterisation of some new hexa-coordinated Schiff base complexes of the type RuCl(CO)(EPh3)(B)(L)] (E = P or As; B = PPh3 or AsPh3 or py or pip; L = anion of the Schiff bases derived from 2-hydroxy-1-naphthaldehyde and aniline, 4-chloroaniline or 2-methylaniline) are reported. I.r., electronic, 1H-n.m.r, 31P-n.m.r. spectra, catalytic activity and antibacterial activity of the complexes are discussed. An octahedral structure has been tentatively proposed for all the complexes. |
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