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Reduction of pyracylene by alkali metals: Mechanism and formation of aggregates |
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| Authors: | Gil Zilber Vladimir Rozenshtein Ari Ayalon Haim Levanon Mordecal Rabinovitz Lawrence T Scott Hope B Warren Gaby Persy Jakob Wirz |
| Institution: | 1. Institute of Chemistry, The Hebrew University of Jerusalem, 91904, Jerusalem, Israel 2. Merkert Chemistry Center, Boston College, 02167-3860, Chestnut Hill, MA, USA 3. Institut für Physikalische Chemie der Universitat Basel, Klingelbergstr 80, CH-4056, Basel, Switzerland |
| Abstract: | Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed. |
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