Crystal and molecular structures of three germylated steroids |
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| Authors: | S A Pogozhikh Yu E Ovchinnikov V N Khrustalev M Yu Antipin R G Karpenko S P Kolesnikov |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(2) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation |
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| Abstract: | Germylated steroids were studied by X-ray diffraction analysis for the first time. The conformational parameters of the molecules
in the crystals are discussed. The three-center hypervalent O−Ge−Cl bonds are observed in two β-isomers. The geometric parameters
of the hypervalent units are compared.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 116–122, January, 1999. |
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| Keywords: | X-ray diffraction analysis steroids germanium derivatives hypervalent bond |
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