1. National & Local Joint Engineering Research Center for Applied Technology of Hybrid Nanomaterials, Henan University Jinming Street Kaifeng, P.R. China;2. Institute of Nanostructured Functional Materials Huanghe Science and Technology College, Zhengzhou, P.R. China
Abstract:
This focus review summarizes our recent efforts on the synthetic applications of bithiophene dicarbanions generated from three bithiophene isomers: 2,2′‐, 3,3′‐, and 2,3′‐bithiophene. Based on these bithiophene dicarbanions, a series of dithienothiophenes ( DTT s) and cyclooctatetrathiophenes ( COTh s) were synthesized by intra‐ and intermolecular cyclizations, respectively. Moreover, recent applications of DTT and COTh in characteristic compounds such as dendrimers, thio[8]circulenes, double helicenes, and thienoacenes are summarized in this account. Besides the synthetic work, some photoelectric properties of the thiophene‐based oligomers including organic field‐effect transistors and organic photovoltaics are briefly reviewed.
