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| Syntheses and Crystal Structures of （PySe）2 and Bi2（PySe）6（HPySe=2-Pyridineselenol N-Oxide） | |
| 引用本文： | 马德良,高明霞,张红剑,沈震,牛德仲. Syntheses and Crystal Structures of （PySe）2 and Bi2（PySe）6（HPySe=2-Pyridineselenol N-Oxide）[J]. 结构化学, 2010, 29(3): 444-448 |
| 作者姓名： | 马德良 高明霞 张红剑 沈震 牛德仲 |
| 作者单位： | Xuzhou;Radio;University;Normal;Institute;Technology;College;Chemistry;Chemical;Engineering; |
| 基金项目： | supported by the Natural Science Foundation of Xuzhou city government (Nos XJ07069 and XJ08069) |
| 摘 要： | The title compounds(PySe)2 1(HPySe=2-pyridineselenol N-oxide,(PySe)2= bis(2-pyridine-N-oxide) diselenide) and Bi2(PySe)6 2 were prepared by the reaction of 2-bromine-N-oxide with NaHSe and Bi(NO3)3·5H2O with HPySe,and the crystal structure of 2 was studied.Compound 2 crystallizes in the monoclinic space group P21/n with a=9.840(2),b=10.204(2),c=18.395(2),β=102.926(2)°,V=1800.0(5)3,Dc=2.2687 g/cm3,Z=2,the final R=0.0319 and wR=0.0646.The Bi atoms are coordinated by four selenium and four oxygen atoms from four PySe ligands to form a slightly distorted four-column geometry. |
| 关 键 词： | 晶体结构 氧化物 合成 标题化合物 几何形状 氧原子 P21 空间群 |
Syntheses and Crystal Structures of (PySe)_2 and Bi_2(PySe)_6(HPySe=2-Pyridineselenol N-Oxide) |
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| MA De-Liang,GAO Ming-Xia,ZHANG Hong-Jian,SHEN Zhen,NIU De-Zhong. Syntheses and Crystal Structures of (PySe)_2 and Bi_2(PySe)_6(HPySe=2-Pyridineselenol N-Oxide)[J]. Chinese Journal of Structural Chemistry, 2010, 29(3): 444-448 | |
| Authors: | MA De-Liang GAO Ming-Xia ZHANG Hong-Jian SHEN Zhen NIU De-Zhong |
| Affiliation: | 1. Xuzhou Radio and TV University,& Chemical Engineering,Xuzhou Normal University,Xuzhou,Jiangsu 221116,China 2. Xuzhou Institute of Technology,& Chemical Engineering,Xuzhou Normal University,Xuzhou,Jiangsu 221116,China 3. College of Chemistry & Chemical Engineering,Xuzhou Normal University,Xuzhou,Jiangsu 221116,China |
| Abstract: | The title compounds(PySe)_2 1(HPySe=2-pyridineselenol N-oxide，(PySe)_2=bis(2-pyridine-N-oxide)diselenide)and Bi_2(PySe)_6 2 were prepared by the reaction of 2-bromine-N-oxide with NaHSe and Bi(NO_3)_3·5H_2O with HPySe，and the crystal structure of 2 was studied.Compound 2 crystallizes in the monoelinic space group P2_1/n with a=9.840(2)，b=10.204(2)，c=18.395(2)A，β=102.926(2)°，V=1800.0(5)A~3，Dc=2.2687 g/cm~3，Z=2，the final R=0.0319 and wR=0.0646.The Bi atoms are coordinated by four selenium and four oxygen atoms from four PySe ligands to form a slightly distorted four-column geometry. |
| Keywords: | 2-pyridineselenol N-oxide X-ray crystallography |
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