ESR spectra and electronic structure of the MoO3+ complex with the dithiocarbamate ligand |
| |
| Authors: | Yu. V. Rakitin A. V. Ivanov |
| |
| Affiliation: | (1) Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials, Kola Research Center of the Russian Academy of Sciences, 26a ul. Fersmana, 184200 Apatity, Murmansk Region, Russian Federation;(2) Amur Complex Scientific-Research Institute, Amur Research Center of Eastern Branch of the Russian Academy of Sciences, 21 Ignat'evskoe shosse, 675000 Blagoveshchensk, Amur Region, Russian Federation |
| |
| Abstract: | ESR spectra of liquid and frozen benzene solutions of isotope-enriched95,97,98MoVO(dtc)3 complexes ([ x Mo]>95%, dtc is theN,N-diethyl dithiocarbamate ligand) and their solid solutions in a matrix of tetraethylthiuram disulfide were studied in the X-range. Comparison of the experimental and calculated parameters of the ESR spectra shows that the axial symmetry of the magnetic tensors does not contradict the low symmetry of the complex, in which the “ylic” oxygen and five of six S atoms in three dithiocarbamate ligands form the coordination sphere of the metal. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2096–2099, November, 1999. |
| |
| Keywords: | molybdenum MoO3+ dithiocarbamate ligand retraethylthiuram disulfide complex ESR spectra electronic structure |
| 本文献已被 SpringerLink 等数据库收录！ |
|
