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ChemInform Abstract: Labile Degree of Disorder in Bismuth‐Oxophosphate Compounds: Illustration Through Three New Structural Types. |
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| Authors: | A Aliev D Endara M Huve M Colmont P Roussel L Delevoye T T Tran P S Halasyamani O Mentre |
| Abstract: | Single crystals of Bi2(Bi1.56K0.44)O3] K0.88(PO4)2 (I), Bi10 (Bi0.5Cd0.5)8O16] (Bi0.6Cd0.8)2(PO4)8 (II), and Bi18Zn10O21] Zn5(PO4)14 (III) are prepared by melting K2CO3 (or CdO or ZnO), Bi2O3, and (NH4)2HPO4 in a 1:1:2 molar ratio (open Au tube, 900—950 °C, 10 h). |
| Keywords: | structure (solids and liquids) bismuth Bi potassium K zinc Zn cadmium Cd phosphorus P |