Abstract: | Kinetic regularities of triphenylphosphite ozonide reaction with triphenylphosphite have been studied at T=–75°C to –40°C. The rate of ozonide consumption is estimated as W=k1(C6H5O)3P·O3]+k2(C6H5O)3P·O3](C6H5O)3P], where k1=(2.03±0.39)×10–5s–1(–50°C), 1gk2=(3.82±0.33)–(6.61±0.32)/gq dm3/mol s and =2.303RT kcal/mol.
![icy](/content/j491051t31821260/xxlarge1080.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![rcy](/content/j491051t31821260/xxlarge1088.gif) ![vcy](/content/j491051t31821260/xxlarge1074.gif) ![acy](/content/j491051t31821260/xxlarge1072.gif) ![lcy](/content/j491051t31821260/xxlarge1083.gif) –75°C ![dcy](/content/j491051t31821260/xxlarge1076.gif) –40°C ![icy](/content/j491051t31821260/xxlarge1080.gif) ![zcy](/content/j491051t31821260/xxlarge1079.gif) ![ucy](/content/j491051t31821260/xxlarge1091.gif) ![chcy](/content/j491051t31821260/xxlarge1095.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![kcy](/content/j491051t31821260/xxlarge1082.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![chcy](/content/j491051t31821260/xxlarge1095.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![scy](/content/j491051t31821260/xxlarge1089.gif) ![kcy](/content/j491051t31821260/xxlarge1082.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![zcy](/content/j491051t31821260/xxlarge1079.gif) ![acy](/content/j491051t31821260/xxlarge1072.gif) ![kcy](/content/j491051t31821260/xxlarge1082.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![mcy](/content/j491051t31821260/xxlarge1084.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![rcy](/content/j491051t31821260/xxlarge1088.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![scy](/content/j491051t31821260/xxlarge1089.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![rcy](/content/j491051t31821260/xxlarge1088.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![acy](/content/j491051t31821260/xxlarge1072.gif) ![kcy](/content/j491051t31821260/xxlarge1082.gif) ![tscy](/content/j491051t31821260/xxlarge1094.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![zcy](/content/j491051t31821260/xxlarge1079.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![dcy](/content/j491051t31821260/xxlarge1076.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![rcy](/content/j491051t31821260/xxlarge1088.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![fcy](/content/j491051t31821260/xxlarge1092.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![lcy](/content/j491051t31821260/xxlarge1083.gif) ![fcy](/content/j491051t31821260/xxlarge1092.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![scy](/content/j491051t31821260/xxlarge1089.gif) ![fcy](/content/j491051t31821260/xxlarge1092.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![rcy](/content/j491051t31821260/xxlarge1088.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![fcy](/content/j491051t31821260/xxlarge1092.gif) ![iecy](/content/j491051t31821260/xxlarge1077.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![lcy](/content/j491051t31821260/xxlarge1083.gif) ![fcy](/content/j491051t31821260/xxlarge1092.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![scy](/content/j491051t31821260/xxlarge1089.gif) ![fcy](/content/j491051t31821260/xxlarge1092.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) . ![Scy](/content/j491051t31821260/xxlarge1057.gif) ![kcy](/content/j491051t31821260/xxlarge1082.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![rcy](/content/j491051t31821260/xxlarge1088.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![scy](/content/j491051t31821260/xxlarge1089.gif) ![tcy](/content/j491051t31821260/xxlarge1090.gif) ![rcy](/content/j491051t31821260/xxlarge1088.gif) ![acy](/content/j491051t31821260/xxlarge1072.gif) ![scy](/content/j491051t31821260/xxlarge1089.gif) ![khcy](/content/j491051t31821260/xxlarge1093.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![dcy](/content/j491051t31821260/xxlarge1076.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![vcy](/content/j491051t31821260/xxlarge1074.gif) ![acy](/content/j491051t31821260/xxlarge1072.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![zcy](/content/j491051t31821260/xxlarge1079.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![ncy](/content/j491051t31821260/xxlarge1085.gif) ![icy](/content/j491051t31821260/xxlarge1080.gif) ![dcy](/content/j491051t31821260/xxlarge1076.gif) : W=k1(C6H5O)3P·O3]+k2(C6H5O)3P·O3](C6H5O)3P], ![gcy](/content/j491051t31821260/xxlarge1075.gif) ![dcy](/content/j491051t31821260/xxlarge1076.gif) k1=(2,03±0,39)·10–5 –1(–50°C); 1g k2=(3,82±0,33)–(6,61±0,32)/ /![mcy](/content/j491051t31821260/xxlarge1084.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![lcy](/content/j491051t31821260/xxlarge1083.gif) · , =2,303·RT ![kcy](/content/j491051t31821260/xxlarge1082.gif) ![kcy](/content/j491051t31821260/xxlarge1082.gif) ![acy](/content/j491051t31821260/xxlarge1072.gif) /![mcy](/content/j491051t31821260/xxlarge1084.gif) ![ocy](/content/j491051t31821260/xxlarge1086.gif) ![lcy](/content/j491051t31821260/xxlarge1083.gif) ![softcy](/content/j491051t31821260/xxlarge1100.gif)
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