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Frequency and temperature dependence of a.c. conductivity of vitreous silver phosphate electrolytes
Authors:M. Cutroni   A. Mandanici   A. Piccolo   C. Fanggao   G. A. Saunders  P. Mustarelli
Affiliation:

a Dipartimento di Fisica dell 'Università di Messina, ctr. Sperone, 98100, Messina, Italy

b School of Physics, University of Bath, Claverton Down, Bath, UK

c Dipartimento di Chimica-Fisica, Università di Pavia, via Tamarelli 16, 27100, Pavia, Italy

Abstract:The a.c. conductivity behaviour in the 20–300 K temperature range has been investigated for (Ag2S)x(AgPO3)1−x and (Ag2SO4)x(AgPO3)1−x glasses at various salt contents (x). The temperature dependence at selected frequencies in the radioand micro-wave region displays several relaxational contributions which are indistinct in the frequency domain. The low temperature experimental data are discussed and a proposed ‘new universality’ has been examined.
Keywords:Glass   Silver phosphate   Relaxation — silver ions
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