Driving Forces of the Self-Assembly of Supramolecular Systems: Partially Ordered Mesophases |
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Authors: | M A Shcherbina S N Chvalun |
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Institution: | 1.Enikolopov Institute of Synthetic Polymeric Materials,Russian Academy of Sciences,Moscow,Russia;2.National Research Center Kurchatov Intitute,Moscow,Russia;3.Karpov Institute of Physical Chemistry,Moscow,Russia |
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Abstract: | The main aspects are considered of the self-organization of a new class of liquid crystalline compounds, rigid sector-shaped and cone-shaped dendrons. Theoretical approaches to the self-assembly of different amphiphilic compounds (lipids, bolaamphiphiles, block copolymers, and polyelectrolytes) are described. Particular attention is given to the mesophase structures that emerge during the self-organization of mesophases characterized by intermediate degrees of ordering, e.g., plastic crystals, the rotation-crystalline phase in polymers, ordered and disordered two-dimensional columnar phases, and bicontinuous cubic phases of different symmetry. |
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