Thermal Decomposition of Triazine Herbicides. I. 1,2-(4-chloro-6-ethylamino-1,3,5-triazin-2-ylamino)-2-methylpropionitrile (cyanazine) |
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Authors: | K Dro?d?ewska A Ksi??czak T Ksi??czak |
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Institution: | (1) Analytical Department, Institute of Industrial Organic Chemistry, Annopol 6, 03-236 Warsaw, Poland;(2) Department of Chemistry, Warsaw University of Technology, Noakowskiego 3, 00-664 Warsaw, Poland |
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Abstract: | Cyanazine was taken as an example for investigations under the influence of different conditions on thermal decomposition
of triazine herbicides. DSC measurements were carried out under atmospheric pressure and hermetically closed, under pressure
1.3 kPa. The influence of the pressure on the constant reaction rate of decomposition of cyanazine was discussed. It was also
proved that the predicted reaction constant rates from isothermal and non-isothermal measurements are consistent.
This revised version was published online in August 2006 with corrections to the Cover Date. |
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Keywords: | cyanazine DSC kinetics thermal stability |
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