Transition metal ion complexes of tiosemicarbazones derived from 2-acetylpyridine. Part 10. A comparison of the chemical and antifungal properties of the copper(II) complexes of 2-acetylpyridine 3-pyrrolidinyl-, 3-piperidinyl-, 3-hexamethyleneiminyl- and 3-azabicyclo[3,2,2]-nonylthiosemicarbazones |
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| Authors: | Douglas X. West Cinda S. Carlson Kevin J. Bouck Anthony E. Liberta |
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| Affiliation: | (1) Department of Chemistry, Illinois State University, 61761 Normal, IL, USA;(2) Department of Biological Sciences, Illinois State University, 61761 Normal, IL, USA |
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| Abstract: | Summary Copper(II) complexes of the 3-pyrrolidinylthiosemicarbazones of 2-acetylpyridine and 2-acetylpyridineN-oxide have been prepared and their physical and spectral properties determined. Growth inhibition ofAspergillus niger, Paecilomyces variotii, Penicillium rubrum, andAspergillus terreus by thiosemicarbazones and their copper(II) complexes has been measured. These results are compared to 2-acetylpyridine 3-azacyclothiosemicarbazone ligand complexes. |
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