Trigonal propeller-shaped [Mn(III)3M(II)Na] complexes (M = Mn, Ca): structural and functional models for the dioxygen evolving centre of PSII |
| |
| Authors: | Nayak Sanjit Nayek Hari Pada Dehnen Stefanie Powell Annie K Reedijk Jan |
| |
| Institution: | Leiden Institute of Chemistry, Leiden University, P.O. Box 9502, 2300 RA, Leiden, The Netherlands. |
| |
| Abstract: | Two new polynuclear heterometallic cluster complexes with Mn(III)(3)M(II)Na] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with Mn(III)Ca(II)Na] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
