Conformational structure of esters of fluorinated acylpyruvic acids |
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Authors: | P N Kondrat'ev Z É Skryabina V I Saloutin M N Rudaya T A Sinitsyna K I Pashkevich |
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Institution: | (1) Institute of Chemistry, Urals Branch, Academy of Sciences of the USSR, Sverdlovsk |
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Abstract: | Esters of fluorinated acylpyruvic acids were obtained for the first time. PMR and IR spectroscopy, dipole moment measurements, and quantum chemical calculations showed that these compounds exist as equilibrium mixtures of E and Z enolic isomers.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1410–1414, June, 1990. |
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