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Cu-Co-Fe oxide catalysts supported on carbon nanotubes for the oxidation of CO
Authors:E. V. Ishchenko  V. K. Yatsimirskii  A. G. Dyachenko  I. V. Kongurova  É. V. Prilutskii
Affiliation:(1) Taras Shevchenko Kyiv National University, Vul. Volodymyrs’ka, 62, Kyiv, 03033, Ukraine;(2) Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Vul. Generala Naumova, 17, Kyiv, 03164, Ukraine;(3) I. N. Frantsevich Institute of Problems of Materials Behavior, National Academy of Sciences of Ukraine, Vul. Krzhyzhanovs’kogo, 3, Kyiv, 03142, Ukraine
Abstract:The catalytic activity and adsorption characteristics of the surface of catalysts in the form of carbon nanotubes produced on nickel and cobalt oxides with the Cu-Co-Fe oxide system as supported active phase were studied. At carbon nanotubes produced on nickel oxide with (10 + 10) wt.% of the catalytically active phase total conversion of CO to CO2 is realized at 47 °C. This sample has high specific surface area and a large volume of mesopores. It was shown that the increase in catalytic activity correlates with the increase in the amount of the α2 form of CO2. __________ Translated from Teoreticheskaya i éksperimental’naya Khimiya, Vol. 42, No. 4, pp. 222–226, July–August, 2006.
Keywords:carbon nanotubes  oxides  catalysis  carbon monoxide
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