[Na4(H2O)7][Fe(OH)6Mo6O18]: A new [12] metallacrown-6 structure with an octahedrally coordinated iron at the center |
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| Authors: | WU Chuande LIN Xiang Yu Rongmin Yang Wenbin LU Canzhong ZHUANG Honghui |
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| Affiliation: | State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Acade-my of Sciences, Fuzhou 350002, China |
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| Abstract: | The reaction of an aqueous solution of sodium molybdate with iron powder at low pH (∼0.184) gives rise to the formation of a six-member Mo ring-shape cluster with an Fe (II) encapsulated at the center, [Na4(H2O)7][Fe(OH)6Mo6O18](1), which is further linked to a remarkable three-dimensional network via sodium ions. |
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| Keywords: | [12] metallacrown-6 structure ring-shaped cluster three-dimensional network ESR |
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