| 层状过渡金属硫代亚磷酸盐及其夹层化合物 |
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| 引用本文： | 陈兴国,张萱,杨楚罗,秦金贵. 层状过渡金属硫代亚磷酸盐及其夹层化合物[J]. 无机化学学报, 2003, 19(5): 449-458 |
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| 作者姓名： | 陈兴国 张萱 杨楚罗 秦金贵 |
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| 作者单位： | 武汉大学化学与分子科学学院,武汉,430072 |
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| 基金项目： | 国家自然科学基金资助项目(No.20072030,90206026,29582001)。 |
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| 摘 要： | 层状过渡金属硫代亚磷酸盐(MPS3)及其夹层物由于所表现出的特殊的固体物理化学性质而受到关注。本文将主要介绍层状过渡金属硫代亚磷酸盐及其夹层物的合成、结构及固体物理性质等方面的研究状况及进展。
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| 关 键 词： | 层状过渡金属硫代亚磷酸盐 夹层化合物 固体物理性质 |
| 修稿时间： | 2002-11-02 |
The Layered Transition Metal Thiophosphates and Their Intercalation Compounds |
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| CHEN Xing-Guo,ZHANG Xuan,YANG Chu-Luo and QIN Jin-Gui. The Layered Transition Metal Thiophosphates and Their Intercalation Compounds[J]. Chinese Journal of Inorganic Chemistry, 2003, 19(5): 449-458 |
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| Authors: | CHEN Xing-Guo ZHANG Xuan YANG Chu-Luo QIN Jin-Gui |
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| Abstract: | The transition metal thiophosphates are layered compounds with the special solid state physical and chemical properties. Except the redox intercalation, some MPS3(M = Mn, Fe, Cd etc.) exhibited a unique non redox intercalation based on the cation exchange route. After intercalation many intercalation compounds based on MPS3 showed some novel physical properties such as ferrimagnetic, photomagnetic and nonlinear optical properties compared to the parent compounds, which makes them be the promising magnetic and photo electronic functional or even multifunctional materials. In this article, the synthesis, structures and solid state physical properties of the layered transition metal thiophosphates and their intercalation compounds have been reviewed. |
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| Keywords: | the layered transition metal thiophosphate intercalation compound solid-state physical properties |
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