The crystal and molecular structure of bis(melamine)silver(I) perchlorate, Ag(C3H6N6)2ClO4 |
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| Authors: | Haoguo Zhu Zhi Yu Xiaozeng You Huaiming Hu Xiaoying Huang |
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| Affiliation: | (1) Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China;(2) State Key Laboratory of Structural Chemistry, Fujian Institute of Research On the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, P. R. China |
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| Abstract: | The crystal structure of the title compound, Ag(mela)2ClO4 (mela = melamine), has been investigated by X-ray diffraction techniques, the crystals are triclinic, space group P1¯, with a = 5.236(2), b = 7.5385(9) c = 19.063(3) Å,  = 99.91(1),  = 90.53(2),  = 108.32(2)° and Z = 2. The Ag atom has a coordination geometry with two strong bonds (2.162(2) and 2.179(4) Å) to the nitrogen of the melamines and two weak bonds (2.776(4) and 2.785(4) Å) to oxygen atoms of the ClO–4anions. The N—Ag—N vector is markedly nonlinear (angle at Ag 167.7(2)°). |
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| Keywords: | Ag(mela)2ClO4 hydrogen bond weak bond |
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