Synthesis of aliphatic ketones from allylic alcohols through consecutive isomerization and chelation-assisted hydroacylation by a rhodium catalyst |
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Authors: | Lee Dae-Yon Moon Choong Woon Jun Chul-Ho |
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Affiliation: | Department of Chemistry, Yonsei University, Seoul 120-749, South Korea. |
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Abstract: | An allylic alcohol, utilized as a precursor for an aliphatic aldehyde, reacted with olefins to afford aliphatic ketones in the presence of RhCl(PPh(3))(3), 2-amino-4-picoline, aniline, and benzoic acid through a tandem reaction of an isomerization and a chelation-assisted hydroacylation. |
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