Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides |
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| Authors: | Bukovec Christian Kazmaier Uli |
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| Institution: | Institut für Organische Chemie, Universit?t des Saarlandes, D-66123, Saarbrücken, Germany. |
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| Abstract: | Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks in excellent yields. |
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