A STUDY OF THE REDOX CHARACTERISTICS OF THE TERNARY CLATHRATE COMPOUND Mo[S2CN(C2H5)2]4}+{FeCl4}-C6H5CH2SSCH2C6H5 |
| |
Authors: | Huang Chubao Guo Chunxiao Zhang Zhigui Xu Lijuan |
| |
Institution: | Department of Chemistry, Jilin University, Changchun |
| |
Abstract: | The redox characteristics of the ternary clathrate compound {MoS2CN(C2H5)2]4}+{C6H5CH2SSCH2C6H5}-was studied by electrochemical measurement and quantum-chemical calculations.The cyclic voltammogram of this ternary clathrate compound in 0.1M KClO4-DMF with a platinum electride had 2.pairs of redox peak.Both the electrochemical parameters derived from the voltammogram and the results of EHMO calculations indicate that the pair of redox peak at relatively positive potentials corresponds to the redox reaction of Fe(Ⅲ)/Fe(Ⅱ) which is irreversible in nature,while the pair of redox peak at more negative potentials corresponds to the redox reaction of Mo(Ⅴ)/ Mo(Ⅱ) which is semi-reversible.The calculations from experiment measurements are fairly agreement with the theoretical calculations. |
| |
Keywords: | |
|
| 点击此处可从《高等学校化学研究》浏览原始摘要信息 |
| 点击此处可从《高等学校化学研究》下载免费的PDF全文 |