| Synthesis and Crystal Structure of the Mixed-quadriligand Bismuth Complex [Bi(S_2CNEt_2)_2(NO_3)]·[1,10-Phen] |
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| 引用本文： | YIN Han-Dong② XUE Sheng-Cai WANG Chuan-Hua (Department of Chemistry,Liaocheng University,Liaocheng,Shandong 252059,China). Synthesis and Crystal Structure of the Mixed-quadriligand Bismuth Complex [Bi(S_2CNEt_2)_2(NO_3)]·[1,10-Phen][J]. 结构化学, 2004, 0(12) |
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| 作者姓名： | YIN Han-Dong② XUE Sheng-Cai WANG Chuan-Hua (Department of Chemistry Liaocheng University Liaocheng Shandong 252059 China) |
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| 作者单位： | Department of Chemistry，Liaocheng University，Liaocheng，Shandong 252059，China |
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| 基金项目： | This project was supported by the National Natural Science Foundation of China (No. 20271025) and Natural Science Foundation of Shandong Province (No. L2003B01) |
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| 摘 要： | 1 INTRODUCTION Some reports on the syntheses and crystal struc-tures of organotin(IV) dithiocarbamate complexes haveappeared in the previous literatures[1～3], but the bis-muth(Ⅲ) complexes with dithiocarbamate have beenscarcely studied[4]. Due to the n…
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Synthesis and Crystal Structure of the Mixed-quadriligand Bismuth Complex [Bi(S_2CNEt_2)_2(NO_3)]·[1,10-Phen] |
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| Abstract: | The mixed-quadriligand bismuth complex [Bi(S2CNEt2)2(NO3)]?[1,10-Phen] has been synthesized, and its crystal structure was determined by X-ray single-crystal diffraction. The crystal belongs to monoclinic, space group P21/n with a = 10.074(17), b = 15.05(2), c = 18.99(3) ?, β = 98.85(3)o, V = 2845(8) ?3, Z = 4, F(000) = 1464, Dc = 1.746 g/cm3, μ = 6.523 mm-1, R = 0.0333 and wR = 0.0703. In this complex, the bismuth atom is eight-coordinated in a capped distorted pentagonal bipyramidal geometry. |
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| Keywords: | bismuth complex N N-diethyldithiocarbamate synthesis crystal structure |
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