A switch based on self-assembled thymine |
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Authors: | Fatih Kalkan Michael Mehlhorn Karina Morgenstern |
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Institution: | Leibniz Universit?t Hannover, Institut für Festk?rperphysik, Abteilung ATMOS, Appelstra?e 2, D-30167 Hannover, Germany. FU Berlin, Institut für Experimentalphysik, FB Physik, Freie Universit?t Berlin, Arnimallee 14, D-14195 Berlin, Germany. |
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Abstract: | The DNA base thymine is deposited at 100?K on Cu(111) and investigated and manipulated by low-temperature scanning tunneling microscopy at 5?K. At submonolayer coverage paired rows are observed. At monolayer coverage a hexagonal commensurate self-assembled layer with the methyl group pointing away from the surface forms. A reversible local manipulation of molecules within the self-assembled layer is demonstrated. This manipulation is interpreted as an out-of-plane relaxation of molecules within the layer induced by the change of the adsorption geometry of individual molecules between two meta-stable orientations. A positive field of 2-4?V leads to this local change in the molecular arrangement, while a field larger than 4?V restores the original geometry. |
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