Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation |
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| Authors: | Sewell Laura J Chaplin Adrian B Weller Andrew S |
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| Affiliation: | Department of Chemistry, Inorganic Chemistry Laboratories, University of Oxford, Oxford, UK OX1 3TA. |
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| Abstract: | The catalytic hydroboration of tert-butylethene using H(3)B·NMe(3) gives RH(2)B·NMe(3). With H(3)B·NMe(2)H tandem hydroboration under mild conditions/dehydrocoupling occurs that produces R(2)B=NMe(2) (R = H, CH(2)CH(2)(t)Bu). |
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