Direct assembly synthesis of metal complex-semiconductor hybrid photocatalysts anchored by phosphonate for highly efficient CO2 reduction |
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| Authors: | Suzuki Tomiko M Tanaka Hiromitsu Morikawa Takeshi Iwaki Masayo Sato Shunsuke Saeki Shu Inoue Masae Kajino Tsutomu Motohiro Tomoyoshi |
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| Institution: | Toyota Central Research & Development Labs. Inc., Nagakute, Aichi 480-1192, Japan. tomiko@mosk.tytlabs.co.jp |
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| Abstract: | Hybrid photocatalysts consisting of a ruthenium complex and p-type photoactive N-doped Ta(2)O(5) anchored with an organic group were successfully synthesized by a direct assembly method. The photocatalyst anchored by phosphonate exhibited excellent photoconversion activity of CO(2) to formic acid under visible-light irradiation with respect to the reaction rate and stability. |
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