Reaction of nickel(II) xanthates with amines and carbon monoxide: Formation of thiourethanes and nickel tetracarbonyl |
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| Authors: | Anna Vizi-Orosz László Markó |
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| Institution: | (1) Research Group for Petrochemistry of the Hungarian Academy of Sciences, H-8200 Veszprém, Hungary |
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| Abstract: | Summary Nickel(II) xanthates react with amines to form nickel(II) dithiocarbamates and thiourethanes, both products of nucleophilic substitution at the sp2 carbon atom. If the reaction is conducted under carbon monoxide the nickel and sulphur-containing byproduct of thiourethane formation is transformed partly into Ni(CO)4. |
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