Leitfähigkeitsuntersuchungen in Hexamethylphosphorsäuretriamid und Propandiol-1,2-carbonat |
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| Authors: | U. Mayer V. Gutmann A. Lodzinska |
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| Affiliation: | 1. Institut für Anorganische Chemie der Technischen Hochschule Wien, ?sterreich
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| Abstract: | Limiting conductances, dissociation constants and ion conductances have been determined for a number of tetrabutylammonium and lithium salts in the solvents hexamethylphosphoric triamide (HMPT) and propanediol-1.2-carbonate (PDC). LiCl and LiBr are completely dissociated inHMPT, but are associated inPDC. The reverse behaviour is found for the corresponding tetrabutylammonium salts. Conductance measurements show thatHMPT is a strongly differentiating solvent for the donor strength of halide and perchlorate ions. |
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