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Some studies on the solid solutions in the systems Sr2Nb2O7Eu2Nb2O7 and Sr2Ta2O7Eu2Ta2O7
Authors:Kazunao Sato  Gin-Ya Adachi  Jiro Shiokawa
Institution:Department of Applied Chemistry, Faculty of Engineering, Osaka University, Yamadakami, Suita-shi, Osaka-fu, 565 Japan
Abstract:Preparation of new solid solutions containing divalent europium have been tried in the systems Eu2Nb2O7Sr2Nb2O7 and Eu2Ta2O7Sr2Ta2O7. These solid solutions described as Eu2xSr2(1?x)M2O7 (M = Nb and Ta) exist in a pure orthorhombic phase in a limited region of x from 0 to about 0.5. The compounds with compositions close to Eu2M2O7 exist but techniques have not been found to prepare them in pure form.
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