| Catalytic Cyclotrimerization of Arylnitriles Using the Novel Samarium(II) Complexes as Catalysts |
| |
| 引用本文： | 徐凡,朱雪华,沈琪,陆俊,李久芹. Catalytic Cyclotrimerization of Arylnitriles Using the Novel Samarium(II) Complexes as Catalysts[J]. 中国化学, 2002, 20(11): 1334-1339. DOI: 10.1002/cjoc.20020201130 |
| |
| 作者姓名： | 徐凡 朱雪华 沈琪 陆俊 李久芹 |
| |
| 作者单位： | XU，Fan a ZHU，Xue-Hua a SHEN，Qi，a，b LU，Jun a LI，Jiu-Qin a aDepartment of Chemistry，Suzhou University，Suzhou，Jiangsu 215006，China bState Key Laboratory of Organometallic Chemistry，Shanghai Institute of Organic Chemistry，C |
| |
| 基金项目： | theNationalNaturalScienceFoundationofChina (No.2 0 0 72 0 2 7) |
| |
| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＴｒｉａｚｉｎｅｓａｒｅｕｓｅｆｕｌｐｒｅｃｕｒｓｏｒｓｏｆｍａｎｙｂｉｏｌｏｇｉｃａｌｌｙａｃｔｉｖｅｃｏｍｐｏｕｎｄｓ ,1 3 ａｎｄｓｅｖｅｒａｌｓ ｔｒｉａｚｉｎｅｓ4 ,5ａｒｅａｌｓｏｒｅｃｏｇｎｉｚｅｄｔｏｂｅｔｈｅｐｏｗｅｒｆｕｌｃｈｅｌａｔｉｎｇａｇｅｎｔｓ .Ｔｈｅｃｏｍ ｍｏｎｍｅｔｈｏｄｓｌｅａｄｉｎｇｔｏｓ ｔｒｉａｚｉｎｅｓｉｎｃｌｕｄｅｏｘｉｄａｔｉｏｎｏｆａｒｏｍａｔｉｃａｌｄｅｈｙｄｅｓａｎｄｃｙｃｌｏｔｒｉｍｅｒｉｚａｔｉｏｎｏｆｎｉｔｒｉｌｅｓ .…
|
Catalytic Cyclotrimerization of Arylnitriles Using the Novel Samarium(II) Complexes as Catalysts |
| |
| XU,Fan a ZHU,Xue-Hua a SHEN,Qi,a,b LU,Jun a LI,Jiu-Qin a a. Catalytic Cyclotrimerization of Arylnitriles Using the Novel Samarium(II) Complexes as Catalysts[J]. Chinese Journal of Chemistry, 2002, 20(11): 1334-1339. DOI: 10.1002/cjoc.20020201130 |
| |
| Authors: | XU Fan a ZHU Xue-Hua a SHEN Qi a b LU Jun a LI Jiu-Qin a a |
| |
| Affiliation: | XU,Fan a ZHU,Xue-Hua a SHEN,Qi,a,b LU,Jun a LI,Jiu-Qin a aDepartment of Chemistry,Suzhou University,Suzhou,Jiangsu 215006,China bState Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,C |
| |
| Abstract: | Samarium(II) complexes or Samarium(II) complexes/n-hexylamine systems were found to be efficient catalysts for cyclotrimerization of arylnitriles. A variety of nitriles can be converted into the corresponding substituted-s-triazines under mild conditions in good to high yields by using samarium(II) complexes/n-hexylamine as catalysts. The same reaction catalyzed by samarium(II) complexes alone gives s-triazines in moderate yields. |
| |
| Keywords: | synthesis catalysis arylnitrile 2 4 6-trisubstituted-s-triazine samarium(II) complex |
| 本文献已被 CNKI 等数据库收录！ |
