| 双(2,4-二甲基戊二烯基)氯化钆的合成及晶体结构 |
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| 引用本文： | 王建辉,母瀛,施展,张所波,冯守华.双(2,4-二甲基戊二烯基)氯化钆的合成及晶体结构[J].高等学校化学学报,2000,21(6):829-831. |
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| 作者姓名： | 王建辉 母瀛 施展 张所波 冯守华 |
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| 作者单位： | 1. 吉林大学化学系;
2. 无机合成与制备化学开放研究实验室, 长春 130023 |
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| 基金项目： | 国家自然科学基金 !(批准号 :2 9672 0 13，2 975 414 3 ) |
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| 摘 要： | 合成双(2,4-二甲基戊二烯基)氯化钆{2,4-(CH3)2C5H5]2GDcl}2,并测定了晶体结构.晶体为单斜晶系,P21/n空间群.晶胞参数a=0.89141(18)nm,b=1.4486(3)nm,c=1.15925(15)nm,β=92.996(18)°,V=1.4949(4)nm3,Z=3.
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| 关 键 词： | 稀土配合物 戊二烯基氯化钆 合成 晶体结构 |
| 收稿时间： | 1999-05-06 |
Synthesis and Structure of Bis(2,4-dimethylpentadienyl)gadolinium Chloride |
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| WANG Jian-Hui,MU Ying,SHI Zhan,ZHANG Suo-Bo,FENG Shou-Hua.Synthesis and Structure of Bis(2,4-dimethylpentadienyl)gadolinium Chloride[J].Chemical Research In Chinese Universities,2000,21(6):829-831. |
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| Authors: | WANG Jian-Hui MU Ying SHI Zhan ZHANG Suo-Bo FENG Shou-Hua |
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| Institution: | 1. Department of Chemistry;
2. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China |
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| Abstract: | Anew complex {〔2,4-(CH3)2C5H5〕2GDcl}2 was obtained by the reaction of 2,4-(CH3)2C5H5]3Gd with GDcl3 in toluene at refluxing temperature. The compound {2,4-(CH3)2C5H5]2GDcl}2 crystallizes in the monoclinic system, space group P21/ n with a =0.89141(18) nm, b =1.4486(3) nm, c =1.15925(15) nm, β = 92.996(18)°, V =1.4949(4) nm3 , Z =3. |
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| Keywords: | Lanthanide complexes Bis(pentadienyl)gadolinium chloride Synthesis Crystal structure |
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