pi-Face donor properties of N-heterocyclic carbenes |
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| Authors: | Süssner Marcus Plenio Herbert |
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| Institution: | Anorganische Chemie im Zintl-Institut des FB Chemie, TU Darmstadt, Petersenstr. 18, 64287, Darmstadt, Germany. |
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| Abstract: | The donor properties of aryl substituted N-heterocyclic carbenes are characterized by lone pair donation from the carbene carbon and, as is shown here, by donation of electron density of the aromatic pi-face of the NHC aryl groups towards the metal. |
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