Ethylenediamine complexes of transition metalbis(chlorosulphates) |
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Authors: | Mohammad Shakir Farha Firdaus Shahul Hameed |
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Institution: | (1) Division of Inorganic Chemistry, Department of Chemistry, Aligarh Muslim University, 202 002 Aligarh, India |
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Abstract: | Summary The number and positions of the i.r. active modes in ethylenediamine complexes of M(SO3Cl)2 (M = Mn, Fe, Co, Ni or Cu) suggest that the SO3Cl– anion is covalently bound in these non-electrolytic complexes. Magnetic moments and ligand field data suggest that each SO3Cl– group is monodentate, giving an octahedral geometry around the metal ions. |
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