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聚(4-乙烯基吡啶)硫酸氢盐: 一个新的高效催化剂用于无溶剂条件下合成13-芳香基-茚并 [1,2-b] 石脑油 [1,2-e] 吡喃-12(13H)-酮(英文)
引用本文:Majid Ghashang,Syed Sheik Mansoor,Krishnamoorthy Aswin. 聚(4-乙烯基吡啶)硫酸氢盐: 一个新的高效催化剂用于无溶剂条件下合成13-芳香基-茚并 [1,2-b] 石脑油 [1,2-e] 吡喃-12(13H)-酮(英文)[J]. 催化学报, 2014, 35(1): 43-48. DOI: 10.1016/S1872-2067(12)60707-4
作者姓名:Majid Ghashang  Syed Sheik Mansoor  Krishnamoorthy Aswin
作者单位:a Faculty of Sciences, Najafabad Branch, Islamic Azad University, Najafabad, Esfahan, Iran;
b Bioactive Organic Molecule Synthetic Unit, Research Department of Chemistry, C. Abdul Hakeem College, Melvisharam -632 509, Tamil Nadu, India
摘    要:

收稿时间:2013-08-05

Poly(4-vinylpyridinium)hydrogen sulfate: A novel and efficient catalyst for the synthesis of 13-aryl-indeno[1, 2-b]naphtha[1, 2-e]pyran-12(13H)-ones under solvent-free conditions
Majid Ghashang,Syed Sheik Mansoor,Krishnamoorthy Aswin. Poly(4-vinylpyridinium)hydrogen sulfate: A novel and efficient catalyst for the synthesis of 13-aryl-indeno[1, 2-b]naphtha[1, 2-e]pyran-12(13H)-ones under solvent-free conditions[J]. Chinese Journal of Catalysis, 2014, 35(1): 43-48. DOI: 10.1016/S1872-2067(12)60707-4
Authors:Majid Ghashang  Syed Sheik Mansoor  Krishnamoorthy Aswin
Affiliation:a Faculty of Sciences, Najafabad Branch, Islamic Azad University, Najafabad, Esfahan, Iran;
b Bioactive Organic Molecule Synthetic Unit, Research Department of Chemistry, C. Abdul Hakeem College, Melvisharam -632 509, Tamil Nadu, India
Abstract:An facile and efficient protocol for the synthesis of 13-aryl-indeno[1,2-b]naphtha[1,2-e]pyran- 12(13H)- ones has been developed that proceeds via the one-pot three-component sequential reaction of an aromatic aldehyde with β-naphthol and 2H-indene-1,3-dione under solvent-free conditions in the presence of a poly(4-vinylpyridinium)hydrogen sulfate (P(4-VPH)HSO4) catalyst. The catalyst can be reused several times, making this procedure facile, practical, and sustainable. The simple experimental procedure, solvent-free reaction conditions, use of an inexpensive catalyst, short react time, and excellent yields are some of the major advantages of this methodology.
Keywords:Poly(4-vinylpyridinium)hydrogen sulfate  Indenonaphthopyrans  2H-indene-1  3-dione  β-Naphthol
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