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Nucleophilic trifluoromethylation with organoboron reagents
Authors:Vitalij V. LevinAlexander D. Dilman  Pavel A. BelyakovMarina I. Struchkova  Vladimir A. Tartakovsky
Affiliation:N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russia
Abstract:Potassium trialkoxy(trifluoromethyl)borates are shown to behave as convenient reagents for nucleophilic trifluoromethylation of non-enolizable aldehydes and N-tosylimines to give CF3-substituted alcohols and N-tosylamines in good yields.
Keywords:Nucleophilic trifluoromethylation   Carbonyl compounds   Imines   Organoboron reagents
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