Tandem multi-step synthesis of C-carboxyazlactones promoted by N-heterocyclic carbenes |
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Authors: | Campbell Craig D Duguet Nicolas Gallagher Katherine A Thomson Jennifer E Lindsay Anita G O'Donoghue Annmarie C Smith Andrew D |
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Institution: | EaStCHEM, School of Chemistry, University of St Andrews, North Haugh, St Andrews, UK KY16 9ST. |
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Abstract: | Cascade reaction sequences incorporating N-heterocyclic carbene-based organocatalysis have been developed that allow the direct preparation of a range of (+/-)-4-phenoxycarbonylazlactones in good isolated yields (66-84%) from the corresponding N-p-anisoyl amino acids. |
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