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3-三苯基锗基-1,1-二苯基-1-丁醇类化合物的拉曼光谱和红外光谱研究
引用本文:王吉有,徐晓轩,郭曙光,金鹏,张存洲,曾宪顺,张正之.3-三苯基锗基-1,1-二苯基-1-丁醇类化合物的拉曼光谱和红外光谱研究[J].光谱学与光谱分析,2000,20(5):668-670.
作者姓名:王吉有  徐晓轩  郭曙光  金鹏  张存洲  曾宪顺  张正之
作者单位:1. 南开大学物理科学学院光子学中心,300071,天津
2. 南开大学元素有机化学研究所,300071,天津
摘    要:我们合成3-三苯基锗基-1,1-二苯基-1-丙醇及同系物3-三苯基锗基-1,1-二苯基-1-丁醇;3-三苯基锗基-2-甲基-1,1-二苯基-1-丙醇,这些化合物都是有机锗类化合物,是具有抗肿瘤活性的化合物3-三苯基锗基-1-二苯基-1-丙醇的类似物,它们可能具有生物活性。我们测量了它们的拉曼光谱及红外光谱。经光谱分析,指认了主要波数所对应的分子振动。在这三种化合物中,Ge-Ph的伸缩振动出现在10

关 键 词:有机锗化合物  拉曼光谱  红外光谱  抗肿瘤活性

Raman Spectra and IR Spectra of 3-triphenylgermyl-1,1-diphenyl-1-butanol and Its Derivatives
Jiyou WANG,Xiaoxuan XU,Shuguang GUO,Peng JIN,Cunzhou ZHANG,Xianshun ZENG,Zhengzhi ZHANG.Raman Spectra and IR Spectra of 3-triphenylgermyl-1,1-diphenyl-1-butanol and Its Derivatives[J].Spectroscopy and Spectral Analysis,2000,20(5):668-670.
Authors:Jiyou WANG  Xiaoxuan XU  Shuguang GUO  Peng JIN  Cunzhou ZHANG  Xianshun ZENG  Zhengzhi ZHANG
Institution:Photonics Center, College of Physical Science, Nankai University, 300071 Tianjin.
Abstract:The Raman spectra and FTIR spectra of 3-triphenylgermyl-1,1-diphenyl-1-propanol (A), 3-triphenylgermyl-1,1-diphenyl-1-butanol (B) and 3-triphenylgermyl-2-methyl-1,1-diphenyl-1-propanol (C) have been measured and analyzed. In Raman spectra of these compounds, the Ge--Ph stretching vibrations are near 1,000 cm-1, and the Ge--C stretching vibrations are 594.1 (for A), 578.7 (for B), 599.2 cm-1 (for C). The spectra show that the three compounds have similar molecular vibration characteristics.
Keywords:Raman spectra    IR spectra    3-triphenylgermy l-1  1-diphenyl-1-propanol    3-triphenylgermyl-1  1-diphenyl-1-butanol    3-triphenylgermyl-2-methyl-1  1-diphenyl-1-propanol
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