First example of an infinite polybromide 2D-network |
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Authors: | Aragoni M Carla Arca Massimiliano Devillanova Francesco A Isaia Francesco Lippolis Vito Mancini Annalisa Pala Luca Slawin Alexandra M Z Woollins J Derek |
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Affiliation: | Dipartimento di Chimica Inorganica ed Analitica, S.S. 554 bivio per Sestu, 09042 Monserrato, Cagliari, Italy. |
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Abstract: | The reaction of the neutral dithiolene [Pd(Et2timdt)2] (Et2timdt = formally monoreduced diethylimidazolidine-2,4,5-trithione) with an excess of Br2 yielded few crystals of [1(Et) x 2Br](2+)(Br-)2(Br2)3 as a by-product (1(Et) = 4,5,9,10-tetrathiocino-[1,2-b:5,6-b']-1,3,6,8-tetraethyl-diimidazolyl-2,7-dithione); X-ray diffraction analysis showed that this compound represents the first example of a polybromide 2D-network templated by [1(Et) x 2Br](+2) dications, and featuring all the Br-Br distances shorter than those found in solid state bromine. |
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