A stable cis-stilbene derivative encapsulated in cucurbit[7]uril |
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Authors: | Choi Soowhan Park Sang Hyun Ziganshina Albina Y Ko Young Ho Lee Jae Wook Kim Kimoon |
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Affiliation: | National Creative Research Initiative Center for Smart Supramolecules, Pohang University of Science and Technology, San 31 Hyojadong, Pohang 790-784, Republic of Korea. |
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Abstract: | cis-Diaminostilbene dihydrochloride encapsulated in cucurbit[7]uril does not spontaneously isomerize to the trans isomer at room temperature as a result of the strong host-guest interactions including strong hydrogen bonds between the two protonated amine termini of the C-shaped guest and the portal oxygen atoms of the host. |
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