Intra- and inter-molecular C-H...F-C and N-H...F-C hydrogen bonding in secondary amine adducts of B(C6F5)3: relevance to key interactions in alkene polymerisation catalysis |
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| Authors: | Mountford Andrew J Hughes David L Lancaster Simon J |
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| Affiliation: | Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK. |
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| Abstract: | The reactions between the cyclic sec. amines pyrrolidine and piperidine with B(C6F5)3 yield Lewis acid-base adducts with both intra- and inter-molecular hydrogen bonding interactions between C-H and N-H groups and aryl-fluorines in the solid state. |
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